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Spider-Man Season 1 (1967) EP8 - Never Step on a Scorpion
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Dr. Stillwell creates the Scorpion on J. Jonah Jameson's behalf to capture Spider-Man. The Scorpion attacks Spider-Man, who escapes. However, the Scorpion's evil nature takes over as his strength increases which causes him to go after Jameson, but Spider-Man captures him and the Scorpion is arrested. However, he breaks out of prison and goes after Jameson again while Spider-Man is searching for him, but Spider-Man arrives in time to fight the Scorpion, who is webbed up and imprisoned again.
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